| 3. | The investigation of structure by x - ray diffraction shows that crystal parameters changes clearly when percenting ca and la into pbtio _ 3 , it was caused by the ca ion and la ion replaced the pb ion of a position in perovskite compound , that bring lattice mismatch and asymmetrical replace 在pbtio _ 3中掺入la和ca可以有效改变薄膜的晶格常数,这是因为在abo _ 3型化合物中,钙离子、镧离子取代了a位的铅离子,造成晶格失配和不对称取代。 |