The reaction is intramolecular and hence fast and clean . 此反应属分子内反应，因而快速且干净利索。
2.
Theoretical study on the stereoselectivity of intramolecular 4 - methyl - 5 - ethenyl - heptanitrile oxide cycloaddition 庚腈氧化物分子内环加成反应的立体选择性
3.
Recognition of anion by dual fluorescent sensor based on the intramolecular charge transfer in p - dimethylaminobenzoylhydrazine 分子内电荷转移双重荧光体识别阴离子研究
4.
Can effectively promote the diazo decomposition and resulted in selective intramolecular n - h insertion . on the other hand , the wolff rearrangement of the 在-重氮羰基化合物的合成应用方面，发现了cu acac
5.
The fluorescence spectra of imidazole derivatives show that the exciplexes were formed between them and acetic acid , respectively . moreover the twist intramolecular charge transfer ( tict ) state was appeared in ( a - pyridyl ) benzoimidazole -吡啶基苯并咪唑可能有分子内电荷转移的性质，而-萘基苯并咪唑和-萘基苯并咪唑表现不出来。
6.
The intramolecular vibrational redistribution ( ivr ) and the ultrafast solvent inertial relaxation should account for the faster decay , while the slower decay is attributed to the diffusive solvent relaxation 快速弛豫过程来源于分子内振动能量再分配( ivr )和溶剂分子超快惯性弛豫动力学过程，而慢速弛豫过程对应于溶剂化的扩散分子弛豫动力学过程。
7.
At the room temperature , fluorescence intensities of these chemosensors in acetonitrile without transition metal ions were found to be very weak , due to the process of the efficient intramolecular photoinduced electron transfer ( pet ) 在室温下对其光物理性质的研究中发现，在没有加入过渡金属离子时，由于体系内存在有效的光诱导电子转移过程使得荧光团的荧光被淬灭。
8.
Abstract : methanesulfonic acid method was used to prepare five acylated chitins . except heptanoyl chitin , four of them , i . e . acetyl chitin , propionyl chitin , butyryl chitin and hexanoyl chitin , had high degree of substitution ( from 1 . 5 to 2 . 0 ) and exhibited lyotropic liquid crystalline behavior and cholesteric phase . as the length of the side chain increased the critical concentration ( w / w ) somewhat increased from 0 . 21 to 0 . 26 because the chain rigidity dropped . the critical concentration values of all the four derivatives were much higher than that of chitin ( 0 . 12 ) due to the decrease of intramolecular hydrogen bonds . the four acylated chitin can form typical banded texture after being sheared . there minimum concentrations to form banded texture of them were evidently different , varied from 0 . 25 ( for acetyl chitin ) to 0 . 37 ( for hexanoyl chitin ) . these results further indicated that liquid crystallinity decreased while the length of flexible side substituents increased 文摘:四种羧酰化甲壳素即乙酰化、丙酰化、丁酰化和己酰化甲壳素在二氯乙酸溶液中均呈现胆甾型溶致液晶相.临界浓度随侧基长度增加而略有增加，衍生物的临界浓度明显都比原甲壳素高许多，这些规律都可以用链刚性的变化来解释.四种羧酰化甲壳素在剪切时均能形成条带织构，而且能形成条带织构的最低浓度有明显差别，随侧基长度增加而提高，进一步表明侧基较长，液晶性减少
9.
Collisonal quantum interference ( cqi ) was observed in the intramolecular rotational energy transfer in the experiment of the static cell , and the integral interference angles were measured . to observe more precise information , the experiment in the molecular beam should be taken , from which the differential interference angle can be obtained precisely . in this paper , the theoretical model of cqi is described in an atom - diatom system in the condition of the molecular beam , based on the first - born approximation of time dependent perturbation theory , taking into accounts the anisotropic lennard - jones interaction potentials . the method of observing and measuring correctly the differential interference angle is presented . the changing tendencies of the differential interference angle with the impact parameter , velocity , and et al . are discussed 分子内部转动传能的静态池实验观察到了碰撞量子干涉效应( cqi ) ,并且测得积分干涉角,为了获得更加精确的分子内部转动传能的碰撞量子干涉效应信息,实验就必须要采用分子束实验进行.本文理论上采用各项异性相互作用势,应用含时微扰理论的一级波恩近似,假想在分子束实验的条件下,建立在原子-双原子分子体系中碰撞量子干涉的理论模型.理论上推导出微分干涉角具体表达式,通过计算定性地讨论了微分干涉角随着碰撞参数、速率等的变化趋势,同时初步探讨了实验的正确观测途径,得出了采用分子束进行实验观测的实验方法,为进一步进行分子束实验提供了理论基础,对实验的进行起到了一定的借鉴作用
