Meso - tetra ( 4 - acyloxyphenyl ) pophyrin was prepared by usual procedure from acyl chloride and meso - tetra ( 4 - hydroxyphenyl ) porphyrin in benzene and obtained in 86 . 4 % yield . treatment of the free base with zinc chloride in dimethyl formamide ( dmf ) - dichloromethane ( ch2cl2 ) yielded corresponding zinc porphyrin complex . the spectral data ( uv - visjr / h - nmr ) and elemental analysis are in agreement with the assigned structures 在合成工作基础上,采用紫外可见光谱( uv - vis ) 、红外光声光谱( ftir - pas ) 、核磁共振氢谱( ~ 1hnmr ) 、元素分析、摩尔电导等手段研究了卟啉及金属卟啉材料的组成及结构。