| 1. | Synthesis of metalloporphyrin and its application to chemical analysis 金属酞菁化合物的合成及其在分析中的应用 |
| 2. | One of metal phthalocyanines was plated , and the effect of reverse saturable absorption performance was discussed after plated 对其中一种金属酞菁化合物进行了蘸膜,探讨了蘸膜后对反饱和吸收特性的影响。 |
| 3. | Five derivatives of metal phthalocyanines were synthesized . the structures of products were characterized by means of ir , hnmr spectra and elementary analysis . and then , the metal phthalocyanine / polymethy methacrylate ( pmma ) were prepared 合成了五种金属酞菁化合物,利用元素分析、红外光谱、核磁共振氢谱等方法,验证了化合物的分子结构。 |
| 4. | By mingling these four kinds of compounds with the monomer ( mma ) of polymethyl methacrylate , respectively , we prepared metal phthaloyanine / polymethyl methacrylate ( pmma ) composite materials which have nonlinear optical properties 分别将四种化合物掺入聚合物单体( mma )中,制备出具有非线性光学性质的金属酞菁/聚甲基丙烯酸甲酯( pmma )复合材料。 |
| 5. | Three derivatives of alkoxy phthalocyanine pb were synthesized as optical limiting materials . the structures of products were characterized by means of ir , hnmr spectra and elementary analysis . and then , the phthalocyanine pb / polymethy methacrylate ( pmma ) were prepared 合成了三种烷氧基取代的金属酞菁铅类光限幅材料,利用元素分析、红外光谱、核磁共振氢谱等方法,验证了化合物的分子结构。 |
| 6. | Phalocyanines are a kind of centrosymmetric planar organo - metallic molecules with an extensively delocalized two dimensional conjugated - electron system which show a relatively large third order optical nonlinearity , varying upon central metal atom substitution and other factors 金属酞菁配合物是一种具有平面共轭电子结构的大环配合物。研究表明,酞菁配合物在可见及近红外波段具有良好的非线性光限幅性能。 |
| 7. | In order to research the application of nonlinear optical materials for optical limiting , four derivatives of alkoxy metal phthaloyanines were synthesized . the structures of the products were characterized by means of ir . 1hnmr spectra and elementary analysis 为探索有机非线性光学材料在光限幅方面的应用,本论文合成了四种烷氧基取代的金属酞菁化合物,并利用元素分析、红外光谱、核磁共振氢谱等方法,验证了化合物的分子结构。 |
| 8. | One of the practicing methods is sol - gel technique , which has been widely used to incorporate a variety of organic and organo - metallic molecules in inorganic host . this paper reports the successful preparation of mpc molecules doped silica gel glass composites obtained by sol - gel technique . the composites are transparent and homogeneous with required optical quality 而从实用化的角度来看,选择理化性能稳定、光学性能好的无机介质作为金属酞菁配合物的载体,不仅对酞菁本身的稳定性,而且对实现酞菁分子的材料化进而器件化有重要意义。 |
| 9. | The relationship between the composites " matrix and dopant component , structure and optical properties is studied . a series of important conclusions and creative achievements are obtained . using pore structure measurement technique , the changes of pore structure of silica gel glass matrix under different sol - gel processing conditions are studied 着重研究了无机基复合金属酞菁材料的制备技术及其成分、结构与光谱学性能的关联、影响和控制规律,并以光限幅性能为应用背景拓展研究,取得了一系列重要结论和创新性成果,为制备新型高效有机无机复合光限幅材料提供了理论依据和物质基础。 |
| 10. | An important issue to be addressed for the successful application of mpc in optical area where will find interesting application is represented by their incorporation in a matrix to fabricate a solid state system . one of the practicing methods is sol - gel technique , which has been widely used to incorporate a variety of organic and organo - metallic molecules in inorganic host 从实用化的角度,选择理化性能稳定、光学透明性好的无机介质作为金属酞菁配合物的载体,制备无机基质酞菁掺杂复合固态材料,不仅对酞菁本身的稳定性,而且对实现酞菁分子的材料化进而器件化有重要意义。 |